DATE : 2°14-01-10
A new study on Electrolytes is now available. According to news reporting originating from Tours, France, by VerticalNews correspondents, research stated, "In this work, we present a study on the physical and electrochemical properties of three new Deep Eutectic Solvents (DESs) based on N-methylacetamide (MAc) and a lithium salt (LiX, with X=bis[(trifluoromethyl).ulfonyl]imide, TFSI; hexafluorophosphate, PF6; or nitrate, NO3). Based on DSC measurements, it appears that these systems are liquid at room temperature for a lithium salt mole fraction ranging from 0.10 to 0.35."
Our news editors obtained a quote from the research, "The temperature dependences of the ionic conductivity and the viscosity of these DESs are correctly described by using the Vogel-Tammann-Fulcher (VTF) type fitting equation, due to the strong interactions between Li(+), X(-) and MAc in solution. Furthermore, these electrolytes possess quite large electrochemical stability windows up to 4.7-5 V on Pt, and demonstrate also a passivating behavior toward the aluminum collector at room temperature. Based on these interesting electrochemical properties, these selected DESs can be classified as potential and promising electrolytes for lithium-ion batteries (LIBs). For this purpose, a test cell was then constructed and tested at 25 °C, 60 °C and 80 °C by using each selected DES as an electrolyte and LiFePO4 (LFP) material as a cathode. The results show a good compatibility between each DES and LFP electrode material. A capacity of up to 160 mA h g(-1) with a good efficiency (99%) is observed in the DES based on the LiNO3 salt at 60 °C despite the presence of residual water in the electrolyte. Finally preliminary tests using a LFP/DES/LTO (lithium titanate) full cell at room temperature clearly show that LiTFSI-based DES can be successfully introduced into LIBs."
According to the news editors, the research concluded: "Considering the beneficial properties, especially, the cost of these electrolytes, such introduction could represent an important contribution for the realization of safer and environmentally friendly LIBs."
For more information on this research see: Deep eutectic solvents based on N-methylacetamide and a lithium salt as suitable electrolytes for lithium-ion batteries. Physical Chemistry Chemical Physics, 2013;15(46):20054-63.
The news editors report that additional information may be obtained by contacting A. Boisset, Universite Francois Rabelais, Laboratoire PCM2E, Parc de Grandmont, 37200 Tours, France. Additional authors for this research include S. Menne, J. Jacquemin, A. Balducci and M. Anouti.
SOURCE : Chemicals & Chemistry
A new study on Electrolytes is now available. According to news reporting originating from Tours, France, by VerticalNews correspondents, research stated, "In this work, we present a study on the physical and electrochemical properties of three new Deep Eutectic Solvents (DESs) based on N-methylacetamide (MAc) and a lithium salt (LiX, with X=bis[(trifluoromethyl).ulfonyl]imide, TFSI; hexafluorophosphate, PF6; or nitrate, NO3). Based on DSC measurements, it appears that these systems are liquid at room temperature for a lithium salt mole fraction ranging from 0.10 to 0.35."
Our news editors obtained a quote from the research, "The temperature dependences of the ionic conductivity and the viscosity of these DESs are correctly described by using the Vogel-Tammann-Fulcher (VTF) type fitting equation, due to the strong interactions between Li(+), X(-) and MAc in solution. Furthermore, these electrolytes possess quite large electrochemical stability windows up to 4.7-5 V on Pt, and demonstrate also a passivating behavior toward the aluminum collector at room temperature. Based on these interesting electrochemical properties, these selected DESs can be classified as potential and promising electrolytes for lithium-ion batteries (LIBs). For this purpose, a test cell was then constructed and tested at 25 °C, 60 °C and 80 °C by using each selected DES as an electrolyte and LiFePO4 (LFP) material as a cathode. The results show a good compatibility between each DES and LFP electrode material. A capacity of up to 160 mA h g(-1) with a good efficiency (99%) is observed in the DES based on the LiNO3 salt at 60 °C despite the presence of residual water in the electrolyte. Finally preliminary tests using a LFP/DES/LTO (lithium titanate) full cell at room temperature clearly show that LiTFSI-based DES can be successfully introduced into LIBs."
According to the news editors, the research concluded: "Considering the beneficial properties, especially, the cost of these electrolytes, such introduction could represent an important contribution for the realization of safer and environmentally friendly LIBs."
For more information on this research see: Deep eutectic solvents based on N-methylacetamide and a lithium salt as suitable electrolytes for lithium-ion batteries. Physical Chemistry Chemical Physics, 2013;15(46):20054-63.
The news editors report that additional information may be obtained by contacting A. Boisset, Universite Francois Rabelais, Laboratoire PCM2E, Parc de Grandmont, 37200 Tours, France. Additional authors for this research include S. Menne, J. Jacquemin, A. Balducci and M. Anouti.
SOURCE : Chemicals & Chemistry